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    Addition polymerisation

    I can describe the formation of an addition polymer from its monomer.

    New
    New

      Addition polymerisation

      I can describe the formation of an addition polymer from its monomer.

      These resources were made for remote use during the pandemic, not classroom teaching.

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      Lesson details

      Key learning points

      1. A polymer is a substance of high average relative molecular mass made up of small repeating units.
      2. In addition polymerisation only one molecule is formed, e.g. addition polymerisation of ethene forms poly(ethene).
      3. Polymers have a specific displayed formula to show repeat units.
      4. A polymer's monomer can be deduced from its structure and vice versa.
      5. Addition polymers can be made by combining together a variety of monomer molecules containing C=C.

      Keywords

      • Polymers - Polymers are long-chained molecules formed by joining together monomers.

      • Monomers - Monomers are small molecules that can join together to form a polymer.

      • Relative molecular mass - The relative molecular mass of a substance is the sum of the relative atomic masses of all the atoms in a molecule.

      • Addition polymerisation - Addition polymerisation is a type of polymerisation where monomers join together to form only one product; a polymer.

      • Repeating unit - The section of a polymer that repeats is known as the repeating unit.

      Common misconception

      Not including the bonds at the end of a repeating unit.

      The slide deck states the need for open bonds to show how repeating units are bonded to each other.

      Use molymods to show how monomers can join together to form polymer chains.
      Teacher tip

      Equipment

      Molymods (optional).

      Licence

      This content is © Oak National Academy Limited (2025), licensed on Open Government Licence version 3.0 except where otherwise stated. See Oak's terms & conditions (Collection 2).

      Lesson video

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      Prior knowledge starter quiz

      Download quiz pdf

      6 Questions

      Q1.
      What is the functional group of alkenes?

      -OH
      Correct answer: C=C
      COOH
      -COO-

      Q2.
      Name the molecule shown in the image.

      An image in a quiz
      Correct Answer: ethene

      Q3.
      What is the relative molecular mass of H₂O?

      Correct Answer: 18

      Q4.
      What is the relative molecular mass of propene (C₃H₆)?

      1
      12
      18
      36
      Correct answer: 42

      Q5.
      Monomers such as styrene can join together to form a polymer. What will the polymer be called?

      poly(ethene)
      Correct answer: poly(styrene)
      poly(tetrafuoroethene)
      poly(vinylchloride)

      Q6.
      Which monomer is used to make poly(propene)?

      ethene
      ethane
      Correct answer: propene
      propanol
      propane

      Assessment exit quiz

      Download quiz pdf

      6 Questions

      Q1.
      How many products are formed during addition polymerisation?

      Correct answer: 1
      2
      3
      4

      Q2.
      Polymerisation of the monomer shown in the image will produce which polymer?

      An image in a quiz
      poly(propene)
      poly(bromoethene)
      Correct answer: poly(chloroethene)
      poly(tetrafluoroethene)

      Q3.
      What is shown in the image?

      An image in a quiz
      Correct answer: a monomer
      a polymer
      a repeating unit

      Q4.
      Match the key terms with the correct definitions.

      Correct Answer:polymers,long-chained molecules formed by joining together monomers.

      long-chained molecules formed by joining together monomers.

      Correct Answer:monomers,small molecules that can join together to form a polymer.

      small molecules that can join together to form a polymer.

      Correct Answer:addition polymerisation,where monomers join together to form only one product.

      where monomers join together to form only one product.

      Correct Answer:repeating unit,a section of a polymer that repeats.

      a section of a polymer that repeats.

      Q5.
      How does the relative molecular mass (Mr) of poly(ethene) compare with the relative molecular mass of ethene?

      Correct answer: The Mr of poly(ethene) is larger than the Mr of ethene.
      The Mr of poly(ethene) is the same as the Mr of ethene.
      The Mr of poly(ethene) is smaller than the Mr of ethene.

      Q6.
      The image shows two repeat units. Which monomer was used in polymerisation to form a polymer containining these repeat units?

      An image in a quiz
      Correct answer: ethene
      propene
      butene
      pentene

      Lesson appears in

      UnitChemistry / Organic chemistry