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      Chemical tests: aqueous ions (including zinc)

      Lesson details

      Learning outcome

      I can perform and interpret sodium hydroxide precipitate tests for metal ions and other tests for identifying ammonium, carbonate, sulfate, and halide ions.

      Key learning points

      1. Some metal ions form coloured precipitates in a reaction with sodium hydroxide solution.
      2. Ammonium ions can be identified by heating with NaOH and using damp red litmus paper, which turns blue if positive.
      3. A dilute acid is usually added before testing for carbonates, sulfates or halides to avoid false positives.
      4. Halide ions produce different coloured precipitates when silver nitrate is added to a solution containing them.
      5. A white precipitate is formed when barium chloride is added to an acidified solution containing sulfate ions.

      Keywords

      • Precipitate - An insoluble solid formed when two solutions react together.

      • Ion - An ion is an atom or group of atoms with a positive or negative charge due to the loss or gain of electrons.

      • Cation - A positively charged ion.

      • Anion - A negatively charged ion.

      Common misconception

      All white precipitates in chemical tests indicate the presence of the same ion without the need for further testing.

      Explain that white precipitates can indicate different ions depending on the test. For instance, barium sulfate indicates sulfate ions, silver chloride indicates chloride ions, and sodium hydroxide tests distinguish between cations.

      Teacher tip

      Emphasise the importance of following proper procedures for each specific test, including using the correct reagents and conditions, to avoid confusion and ensure accurate results.

      Equipment

      NaCl, CaSO₄, Na₂SO₄, BaCl₂, HCl, AgNO₃, HNO₃, pipettes, test tubes, test tube racks, limewater, delivery tubes, bungs, boiling tubes

      Content guidance

      Risk assessment required - chemicals

      Risk assessment required - equipment

      Supervision

      Adult supervision required

      Licence

      This content is © Oak National Academy Limited (2026), licensed on Open Government Licence version 3.0
      except where otherwise stated. See Oak's terms & conditions
      (Collection 2).

      Lesson video

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      Prior knowledge starter quiz

      6 Questions

      Q1.
      Which particle does an atom lose or gain one or more of to form an ion?

      proton
      Correct answer: electron
      neutron

      Q2.
      What does litmus paper indicate?

      the concentration of ions in a solution
      the presence of metal ions
      Correct answer: whether a solution is acidic or basic
      the pH value of a solution

      Q3.
      What is the charge of a cation?

      Correct answer: positive
      negative
      neutral

      Q4.
      Which of the following is a common laboratory acid?

      ethanoic acid
      Correct answer: hydrochloric acid
      carbonic acid
      citric acid

      Q5.
      Which of the following are basic laboratory techniques?

      Correct answer: heating solutions
      Correct answer: performing chromatography
      using a spectrometer

      Q6.
      What does a basic understanding of chemical reactions include?

      Correct answer: knowing how to write and balance chemical equations
      understanding complex organic synthesis
      using advanced analytical techniques

      6 Questions

      Q1.
      What colour precipitate does copper(II) form with sodium hydroxide?

      Correct answer: blue
      brown
      green
      yellow

      Q2.
      Which gas is released when ammonium ions are heated with sodium hydroxide?

      Correct answer: ammonia
      hydrogen
      oxygen
      carbon dioxide

      Q3.
      What colour does damp red litmus paper turn in the presence of ammonia gas?

      purple
      green
      Correct answer: blue
      it doesn't change colour

      Q4.
      What colour precipitate is formed when silver nitrate is added to a solution containing chloride ions?

      cream
      Correct answer: white
      yellow
      grey

      Q5.
      Why is dilute nitric acid added before testing for halides?

      to enhance the colour of the precipitate
      Correct answer: to remove any carbonates that might interfere with the test
      to neutralise the solution
      to form halide ions in solution

      Q6.
      What precipitate is formed when barium chloride is added to an acidified solution containing sulfate ions?

      green
      blue
      Correct answer: white
      brown

      To help you plan your 11 chemistry lesson on: Chemical tests: aqueous ions (including zinc), download all teaching resources for free and adapt to suit your pupils' needs...