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      Condensation polymerisation

      Lesson details

      Learning outcome

      I can explain the basic principles of condensation polymerisation.

      Key learning points

      1. Condensation polymerisation requires monomers with two functional groups.
      2. Condensation polymers can be made of two different monomers.
      3. A polyester is formed by reaction of a monomer with two carboxylic acid groups with a monomer with two alcohol groups.
      4. In condensation polymerisation as well as the polymer a small molecule is formed, usually water.
      5. Amino acids contain two functional groups and can form polypeptides and proteins.

      Keywords

      • Condensation polymerisation - Condensation polymerisation is a type of polymerisation where monomers join together to form a polymer and a small molecule such as water.

      • Addition polymerisation - Addition polymerisation is a type of polymerisation where monomers with a C=C double bond join together to form only one product, a polymer.

      • Polyesters - Polyesters are condensation polymers formed from monomers containing carboxylic acid and alcohol groups. They contain ester bonds.

      • Polyamides - Polyamides are condensation polymers formed from monomers containing carboxylic acid and amine groups. They contain amide bonds.

      • Polypeptides - Polypeptides are condensation polymers formed from amino acids. They contain peptide bonds.

      Common misconception

      Thinking that all polymers are only made up of one monomer. Also, confusing condensation reactions to think that it means to condense and take up less space.

      Examples are shown where more than one monomer is used to make condensation polymers. Discuss what condensation is, and how condensation polymerisation produces water or other small molecules depending on the monomers used.

      Teacher tip

      Molymods are useful to model how the polymer forms and a small molecule.

      Licence

      This content is © Oak National Academy Limited (2026), licensed on Open Government Licence version 3.0
      except where otherwise stated. See Oak's terms & conditions
      (Collection 2).

      Lesson video

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      Prior knowledge starter quiz

      6 Questions

      Q1.
      Which of the following statements about addition polymerisation are correct?

      Correct answer: addition polymerisation results in the formation of one product
      addition polymerisation results in the formation of two products
      Correct answer: addition polymers are made from alkene monomers
      addition polymers are made from alcohol and carboxylic acid monomers

      Q2.
      Which homologous series does this compound belong to?

      An image in a quiz
      alkanes
      alkenes
      Correct answer: alcohols
      carboxylic acids
      esters

      Q3.
      Name the molecule shown in the image

      An image in a quiz
      ethanol
      propanol
      Correct answer: ethanoic acid
      propanoic acid

      Q4.
      Identify the functional groups present in the molecule shown in the image

      An image in a quiz
      C=C
      Correct answer: -COOH
      Correct answer: -OH
      Correct answer: -COO-
      -NH₂

      Q5.
      Which two reactants can react together in the presence of an acid catalyst to produce this compound?

      An image in a quiz
      ethane
      ethene
      Correct answer: ethanol
      Correct answer: ethanoic acid
      ethyl ethanoate

      Q6.
      The image shows an amino acid. How many functional groups are present in this amino acid?

      An image in a quiz
      1
      Correct answer: 2
      3
      4
      5

      6 Questions

      Q1.
      Which homologous series does the molecule in the image belong to?

      An image in a quiz
      alkane
      alkene
      alcohol
      carboxylic acid
      Correct answer: ester

      Q2.
      Which of the following statements about condensation polymerisation are true?

      condensation polymerisation produces 1 product
      Correct answer: condensation polymerisation produces 2 products
      Correct answer: monomers of condensation polymerisation contain at least 2 functional groups
      monomers of condensation polymerisation contain the C=C functional group

      Q3.
      Which polymer could be formed from the following monomer?

      An image in a quiz
      poly(ethene)
      polyester
      Correct answer: polyamide
      poly(vinyl chloride)

      Q4.
      When this monomer polymerises what will be produced?

      An image in a quiz
      polyamide
      Correct answer: polyester
      hydrogen chloride
      Correct answer: water
      hydrogen

      Q5.
      A section of a polymer is shown in the image. Which two monomers could join together to form this polymer?

      An image in a quiz
      dialcohol
      Correct answer: dicarboxylic acid
      Correct answer: diamine
      dihaloalkane

      Q6.
      Which keyword is used to describe condensation polymers formed from amino acids?

      Correct Answer: polypeptides, polypeptide, proteins, protein

      To help you plan your 11 chemistry lesson on: Condensation polymerisation, download all teaching resources for free and adapt to suit your pupils' needs...