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      Lesson details

      Learning outcome

      I can explain why increasing pressure, surface area or concentration increases the frequency of collisions between particles and therefore the rate of reaction.

      Key learning points

      1. Particles of reactants in a chemical reaction can react together if they collide with sufficient energy.
      2. Increasing surface area of a solid lets more reacting particles in a solution collide with its particles each second.
      3. Increasing concentration of a reacting solution introduces more reactant particles, so they collide more frequently.
      4. Increasing temperature of reactants increases the speed of particles, so they collide more frequently.
      5. Increasing pressure of reacting gases pushes reactant particles closer together, so they collide more frequently.

      Keywords

      • Collision theory - The collision theory is that particles must collide, and with sufficient energy, in order to react.

      • Activation energy - The minimum energy that the particles must have in order to react is known as the activation energy.

      • Rate of reaction - Rate of reaction is the speed with which a chemical reaction takes place, measured by the amount of a reactant used or amount of product formed in a given time.

      Common misconception

      That every collision between reactant particles results in a chemical reaction.

      The slide deck addresses that not every collision between reactant particles results in a chemical reaction. The particles must collide with the activation energy in order for the collision to be successful and a new product be formed.

      Teacher tip

      An engaging way to model the idea of increasing concentration, pressure, surface area and temperature is using students to represent the particles in the reactants.

      Equipment

      None required.

      Licence

      This content is © Oak National Academy Limited (2025), licensed on Open Government Licence version 3.0
      except where otherwise stated. See Oak's terms & conditions
      (Collection 2).

      Lesson video

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      Prior knowledge starter quiz

      6 Questions

      Q1.
      In the following reaction identify the reactant: hydrogen peroxide → water + oxygen

      Correct answer: hydrogen peroxide
      hydrogen
      water
      oxygen
      energy

      Q2.
      Which solution has the highest concentration?

      0.5 g/cm³
      1.0 g/cm³
      Correct answer: 2.0 g/cm³
      0.1 g/cm³

      Q3.
      Which of the following statements about rate of reaction are true?

      Correct answer: It is the speed with which a chemical reaction takes place.
      It can be measured by the amount of reactant used × time taken.
      Correct answer: It can be measured by the amount of reactant used ÷ time taken.
      It can be measured by the amount of product formed.
      It can be measured by the amount of product formed × time taken.

      Q4.
      A student has 5 g of calcium carbonate. How can they increase the surface area of the calcium carbonate?

      heat the calcium carbonate
      use a mass of 10 g of calcium carbonate
      increase the density of the calcium carbonate
      Correct answer: crush the calcium carbonate

      Q5.
      On a volume versus time graph, what does a steep gradient represent?

      Correct answer: a high rate of reaction
      the rate of reaction is zero
      a low rate of reaction
      the rate of reaction is not affected by the variable

      Q6.
      Match the key term to the correct definition.

      Correct Answer:collision theory,particles must collide, and with sufficient energy, in order to react

      particles must collide, and with sufficient energy, in order to react

      Correct Answer:activation energy,the minimum energy that the particles must have in order to react

      the minimum energy that the particles must have in order to react

      Correct Answer:concentration,the amount of chemical dissolved in a certain volume of solution

      the amount of chemical dissolved in a certain volume of solution

      Correct Answer:surface area,is the total area of every outer surface of an object

      is the total area of every outer surface of an object

      6 Questions

      Q1.
      Which conditions must particles of reactants meet in order to react in a chemical rection?

      they must be in a liquid state
      they must be in a gaseous state
      they must have similar energy
      Correct answer: they must collide with sufficient energy
      thy must be at a high concentration

      Q2.
      How does increasing the surface area of a solid affect the rate of reaction?

      it decreases the rate of reaction
      Correct answer: it increases the rate of reaction
      it has no effect on the rate of reaction
      it changes the colour of the reaction

      Q3.
      Why does increasing the concentration of reactants typically increase the rate of reaction?

      it increases the size of the reactant particles
      it decreases the number of successful collisions
      it increases the number of successful collisions
      it decreases the speed of reactant particles
      Correct answer: it increases the frequency of successful collisions

      Q4.
      What happens when the concentration of a reacting solution is increased?

      Correct answer: the reactant particles are more likely to collide
      the speed of particles decreases
      the particles are more spread out
      the reaction becomes slower
      Correct answer: there are more reactant particles in the same volume

      Q5.
      What effect does decreasing the pressure of reacting gases have on the rate of reaction?

      it increases the frequency of collisions
      the particles move closer together
      it increases the pressure of the gases
      Correct answer: it decreases the frequency of collisions
      more particles have energy higher than the activation energy

      Q6.
      What effect does increasing the temperature of reactants have on the rate of reaction?

      it decreases the speed of particles
      Correct answer: it increases the kinetic energy of particles
      it decreases the number of collisions
      Correct answer: it increases the frequency of successful collisions
      it increases the number of particles exposed on the surface of a solid reactant

      To help you plan your 10 chemistry lesson on: Collision theory, download all teaching resources for free and adapt to suit your pupils' needs...