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      Lesson details

      Learning outcome

      I can describe the properties of diamond and graphite and explain how they result from their giant covalent structures, as well as relate them to their uses.

      Key learning points

      1. In diamond each carbon atom is bonded to four others with strong covalent bonds to form a giant covalent structure.
      2. Diamond is very hard, has a very high melting point and does not conduct electricity (makes it good for cutting tools).
      3. In graphite, each carbon atom is covalently bonded to three others to form layers of hexagonal rings.
      4. There are only weak forces between the layers in graphite which can easily be rubbed apart (makes it a good lubricant).
      5. Graphite conducts electricity because it has delocalised electrons which can move and carry charge/current.

      Keywords

      • Allotrope - A different structural form of an element, e.g. graphite and diamond are allotropes of carbon.

      • Giant covalent - A large regular arrangement of atoms all joined together by covalent bonds.

      • Forces of attraction - Forces of attraction refer to any force that causes two or more substances to come together.

      • Delocalised - Particles are said to be delocalised when they are free to move through a structure (delocalised electrons can carry an electrical current).

      Common misconception

      Students may think all carbon forms are alike, ignoring structure's impact on properties.

      Emphasise structure-property relationships. Use models to show how diamond's and graphite's differing bonds affect their characteristics.

      Teacher tip

      Use interactive 3D models to demonstrate lattice structures. Compare physical samples of graphite and diamond (crystal/glass are useful substitutes - just don't test the hardness!) to highlight differences.

      Licence

      This content is © Oak National Academy Limited (2026), licensed on Open Government Licence version 3.0
      except where otherwise stated. See Oak's terms & conditions
      (Collection 2).

      Lesson video

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      Prior knowledge starter quiz

      6 Questions

      Q1.
      The presence of which type of bond is a key feature in giant covalent structures?

      Ionic bonds
      Correct answer: Covalent bonds
      Metallic bonds

      Q2.
      Which property is typical of substances with giant covalent structures?

      Correct answer: high melting and boiling points
      conductivity in their solid state
      low melting and boiling points
      soluble in water

      Q3.
      What distinguishes a giant covalent structure from a simple molecular structure?

      the type of atoms involved
      the presence of ionic bonds
      Correct answer: the size and regularity of the structure
      their electrical conductivity
      their solubility in water

      Q4.
      Which diagram below shows a model of a giant covalent substance?

      sodium chloride (NaCl)
      Correct answer: silicon dioxide (SiO₂)
      nitrogen (N₂)
      iron (Fe)

      Q5.
      Which properties are typically found in simple molecular substances but not in giant ionic structures?

      high electrical conductivity
      Correct answer: inability to dissolve in water
      Correct answer: low melting and boiling points
      flexibility and malleability

      Q6.
      In giant covalent structures, atoms are bonded covalently in a large 3D lattice resulting in high melting and boiling points. Match each part of this sentence to the correct term.

      Correct Answer:bonding,covalent

      covalent

      Correct Answer:structure type,giant covalent

      giant covalent

      Correct Answer:property,high melting and boiling points

      high melting and boiling points

      Correct Answer:structure description,large 3D lattice

      large 3D lattice

      6 Questions

      Q1.
      What is an allotrope?

      a type of chemical bond
      Correct answer: a different structural form of an element
      a kind of molecular geometry
      a category of organic compounds

      Q2.
      What makes diamond so hard?

      intermolecular forces
      delocalised electrons
      hexagonal rings
      Correct answer: covalent bonds

      Q3.
      Why can graphite be used as a lubricant?

      strong covalent bonds within atoms
      Correct answer: weak intermolecular forces between layers
      delocalised electrons
      high melting point
      ability to conduct electricity

      Q4.
      In diamond, each carbon atom forms covalent bonds.

      Correct Answer: 4, four

      Q5.
      True or false? In graphite, each carbon atom is bonded to four other carbon atoms.

      True
      Correct answer: False

      Q6.
      Graphite conducts electricity because it has which can move and carry charge/current.

      Correct Answer: delocalised electrons

      To help you plan your 10 combined science lesson on: Diamond and graphite, download all teaching resources for free and adapt to suit your pupils' needs...