Electrolysis of molten salts
I can explain why salts can be electrolysed when in their liquid state, and describe the reactions taking place.
- Year 11
- OCR
Electrolysis of molten salts
I can explain why salts can be electrolysed when in their liquid state, and describe the reactions taking place.
Lesson details
Key learning points
- A solid ionic compound cannot conduct electricity.
- Salts are ionic compounds which can be electrolysed when they are in the molten state.
- Gases may be formed at the electrodes.
- Freely moving ions can reach the electrodes and undergo oxidation or reduction.
- A non-metal always forms at the positive electrode, and a metal forms at the negative electrode.
Keywords
Molten - the term used to describe a liquid substance formed by heating ionic compounds and metal ores.
Anode - A positively charged electrode, in an electrolysis cell, to which the anions are attracted.
Cathode - A negatively charged electrode, in an electrolysis cell, to which the cations are attracted.
Anion - A negatively charged ion.
Cation - A positively charged ion.
Common misconception
Pupils often think that, during electrolysis, the charge carriers are electrons and not ions.
Revisit the structure of ionic compounds in the solid and liquid states. Point out that there are no delocalised electrons. The electrons are associated with ions and so are unable to move through the electrolyte. Ions can move in the liquid state.