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      Instrumental analysis and flame tests: including barium

      Lesson details

      Learning outcome

      I can identify metal ions based on the colour of their flame tests and understand how instrumental analysis methods are used for detecting and identifying elements.

      Key learning points

      1. Positive ions burn with distinct colours that are visible when heated above a blue Bunsen flame.
      2. Instrumental methods are accurate, sensitive, and rapid for detecting and identifying elements and compounds.
      3. Unique flame emission spectra are produced for each positive metal ion.
      4. A spectrometer can split light from coloured flames into flame emission spectra.
      5. A spectrometer can measure more than one metal ion in a single solution and the concentration of each.

      Keywords

      • Flame test - A test where a chemical put into a flame produces a characteristic colour (tests for metal ions).

      • Spectroscope - An instrument that separates light into its component wavelengths.

      • Ion - An ion is an atom or group of atoms with a positive or negative charge due to the loss or gain of electrons.

      • Concentration - The amount of a solute dissolved in a certain volume of solvent.

      • Calibration curve - A graph used to determine the concentration of a substance in a sample.

      Common misconception

      Flame colours are unique, even in mixtures.

      Explain that strong colours, like sodium's yellow, can mask others. Use spectrometry to identify masked elements.

      Teacher tip

      Ensure safety precautions are followed; use clean equipment to avoid contamination during flame tests.

      Equipment

      Bunsen burner setup, 'unknown' metal salt samples to do flame tests, nichrome wire loops, dilute hydrochloric acid, beakers, matches.

      Content guidance

      Risk assessment required - chemicals

      Risk assessment required - equipment

      Supervision

      Adult supervision required

      Licence

      This content is © Oak National Academy Limited (2026), licensed on Open Government Licence version 3.0
      except where otherwise stated. See Oak's terms & conditions
      (Collection 2).

      Lesson video

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      Prior knowledge starter quiz

      6 Questions

      Q1.
      Which of the following particles are not found in the nucleus of an atom?

      protons and neutrons
      electrons and protons
      neutrons and electrons
      Correct answer: electrons only

      Q2.
      What charge does an ion have if it has gained electrons?

      positive
      neutral
      Correct answer: negative

      Q3.
      Which part of the atom is involved in chemical bonding?

      Correct answer: electrons
      neutrons
      protons
      the nucleus

      Q4.
      Which of the following is a general property of metals?

      poor conductors of heat
      brittle
      Correct answer: good conductors of electricity
      dull appearance
      insulators

      Q5.
      Where are metals generally located on the periodic table?

      top right
      top left
      bottom right
      bottom right
      Correct answer: left and centre

      Q6.
      What is an ion?

      an atom that has lost or gained protons
      a neutral atom
      Correct answer: an atom that has lost or gained electrons
      an atom with more protons than neutrons

      6 Questions

      Q1.
      What is the purpose of a flame test?

      to test for non-metal elements
      Correct answer: to identify metal ions by the colour of the flame
      to determine the conductivity of a metal
      to measure the temperature of a flame

      Q2.
      What flame colour does potassium produce?

      yellow
      green
      Correct answer: lilac
      blue

      Q3.
      Why is it important to clean the wire loop before conducting a flame test?

      to prevent the flame from extinguishing
      Correct answer: to avoid contamination from previous tests
      to increase the temperature of the flame
      to remove excess metal ions
      to test multiple ions at once

      Q4.
      What happens to electrons in metal ions when they absorb energy from the flame?

      They lose energy and stay at the same level.
      Correct answer: They move to a higher energy level.
      They leave the atom permanently.
      They remain in the same orbit.

      Q5.
      Why do different metal ions produce different flame colours?

      Correct answer: due to different electron arrangements in each metal ion
      the flame temperature changes for each metal
      the test uses different flames for each metal
      different ions release more light

      Q6.
      What is emitted when electrons in metal ions return to their ground state after excitation?

      heat
      Correct answer: light
      sound

      To help you plan your 11 chemistry lesson on: Instrumental analysis and flame tests: including barium, download all teaching resources for free and adapt to suit your pupils' needs...